Allan,
It depends on the subject. If the subject has a blown out core, for example, in the 10-minute master, but, it's not in the 5-minute master, layer the 10-minute master over the top of the 5-minute master, and via masking, blend the two together.
Otherwise, going along the lines of what you've said, I'd probably lay the 5-minute master over the top and blend via opacity until you're happy with the result. Though, to be honest, I can't see any visible gain from layering a 5-minute master over the top. I would have thought it'd be better to combine all the individual 10-minute and 5-minute (calibrated) exposures using your pre-processing software.
Regards,
Humayun
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