hi David could it be bad flats calibration looks like one of mine I did a while back and the flat frames didnt calibrate properly the image it self looks ok .
cheers Pete
Another possibility: Light leaks via the viewfinder. Being essentially a small optical path that receives light bounced off the prism and mirror inside the camera, it often does the reverse of its job too. Light enters through the viewfinder and bounces off the prism and mirror and then goes onto the sensor. Google "nikon d800 light leak"
aberrations shown by Rowland looks like chromatic abberations, maybe caused by capturing low to the horizon or perhaps a misalignment of lenses in the imaging train (not square).
the white hazy part looks like bad flats - or not using any flats at all - it could be a light leak but i suspect it isn't as usually they are more irregular - to be sure turn it off live view before capture.
attached i did a bit of artificial flat creation and then subtraction.