3D printing is nowhere near good enough, you have a lot to learn about
:
- the surface smoothness required to make a useable mirror,
- the dimensional accuracy required to make a useable telescope mirror,
- the mechanical stiffness of the material (ie does it deform under its own weight outside the above tolerances),
- the thermal characteristics of the material chosen, ie does it expand/contract, soften, deform or sag,
- can the material be polished ? (many plastics cannot be polished)
- how to apply a reflective coating,
- whether the material can be coated in a vacuum (metallic vapour deposition) or a liquid bath (silvering process) or not,
- whether the coating will stick or fall off quickly,
- ability to survive cleaning.
Basically you can forget plastics for anything bigger than 5 cm. The main problem is they are too mechanically weak (they sag under their own weight), achieving the desired surface accuracy is next to impossible, and the uncontrollable deformation (warping) that occurs when the material is warmed.
The materials I'm aware of for successful mirrors are:
Speculum metal (copper/tin alloy),
Obsidian (natural volcanic glass),
Mercury (as a liquid, spinning),
Glass, common borosilicate or flint;
Pyrex and variants,
Fused quartz,
Natural diamond,
Cervit, Sitall and Zerodur, which are all glass-ceramics;
"Siliconised" silicon carbide,
Beryllium, aluminium, gold
Optical plastics
http://www.plasticoptics.com/optical...materials.html
for which processes to cast or grind & polish exist. Some can be reflectively coated, some can't.
Composites, foams and microsphere arrays have also been tried, finding a way to achieve an adequate polish, accurate figure and apply a reflective surface is the main problem as they out-gass in a vacuum, so a vacuum-deposition process can't be used. Mostly these can be used to create a mirror with a surface created by casting against a polished surface, though the surface accuracy is rarely as good as 1 wavelength - which is nowhere near good enough for visual astronomy.
http://www.dtic.mil/cgi-bin/GetTRDoc?AD=ADA532018
Small mirrors are easy - use glass. Past 15 cm, with glass the mechanical stiffness (it sags under its own weight) and thermal expansion becomes an issue and while thin glass mirrors are used for dob mirrors up to 40cm, Pyrex is a lot better material. Beyond 50cm Zerodur, Cervit etc.
There is one other material whose name I have forgotten - its a low density porous sintered black glassy ceramic, on which a top layer of glass has been applied that is thick enough to grind and polish to make a mirror. It has been around for 10 years or so and has been used for amateur mirrors.