Hi Leon,
My 2 cents,
(1) Image one is your master flat from another thread
(2) Image two is the histogram of the master flat
(3) Image three is the threshhold from ps2
You have a vignetting problem. You can see this with the threshold version of the master flat, a clear circle.
As Fred said, your flats are too bright and quite simply are not correcting your light. Have you taken any with the histogram moved left to the left hand 1/4 to 1/3, not like your master flat which is smack bang in the middle.
When you apply your too bright master flat you will not remove the vignetting. So take some correct ones and apply them.
Paul