I think I have finally got it all nutted out, from the polar alignment, to guiding.
Today I set up my ED100 with my ED80 guiding with a Starshoot, all on an NEQ6 mount, aligned via a solar noon reading and an accurate compass (not once have I used the polar scope).
I have been getting GOOD steady 5 minute subs, with the Starshoot set to refresh every 0.5s - that's in calm weather, or like tonight, moderate wind with some smoke about. I decided to try 10 minutes sub...
NO TRAILS whatsoever! PERFECT stars. Great, so I get adventurous - 20 minutes....
SAME RESULT! (I had the ISO at 600). So, I did 1 x 10 minute on the Horsehead, and 1 x 20 minute on the horsehead... whilst a good lot of orange pollution crosses the photo, I can clean that up.
Right now - 0331 - I am doing a 10 minute / ISO 400 / refresh 0.5s on guiding on NGC 3372.
I'll post pictures after uploading and editing later in this fine day.