The compass will point to the magnetic pole of the earth - which is not identical with the celestial pole, e.g. "true south".
You simply turn the compass such that the needle sits on 12 degrees east of S. That direction then is "true south".
Here, the solar noon method as well as the compass emthod are described.
(I bought a simple compass from an outdoor store. But it turned out that my iPhone compass is indeed just as accurate when set to "true north".
Location service: on- Wifi and Bluetooth: off.
I also downloaded Commander Compass Lite which has the advantage of showing whether the iPhone is held level. It can be set to "true north" instead of magnetic north. Then, the needle already points to the SCP when it sits on S - it has then internally adjusted for the declination of your 12.x degrees.
For my mount setup in the drive way, the solar noon method proved to be the best because then I have a long line on the concrete to help me with the orientation of my mount.)