Like Chris said, f5.6- F6.3, the bigger the number, the tighter the stars and the less coma.
ISO 400 makes a smoother picture and more colour in your stars I reckon.
It does mean you need to take more subs, but it's well worth it.
For more instant gratification, go ISO 800 or ISO1600. Just don't be tempted to go to a faster F stop or you'll compromise the edges of your image pretty badly.
Just check your first sub, zoom in around the edges and see what your stars look like. Experiment with settings.
Good luck, you're going to have a great time.