G'day Mark,

to IIS!
A 10" dob is a magnificent instrument. Yes, you can retrofit a Go-to system to it, though it isn't a cheap exercise. A bit more on this later.
You can get planetary cameras with software from the likes of Celestron and Meade. You can talk to
Andrews Communications and
The Binocular and Telescope Shop about these.
You can use either paper charts or computer based software to find your way around the sky, including mobile apps. Which ever way you go, you can find literally thousands of Deep Sky Objects (DSO's) with these and your 10" scope. The Beginners Talk forum has several sticky threads that list many excellent charts.
Binoculars are also very useful. The 7X50 type are considered the classic astronomy size. There are actually some DSO's that are best viewed with binos! They are also magnificent as rich field scopes for wide expansive views.
The only other bit of gear I'd suggest is a torch that has its face covered with two or three layers of red cellophane. Red light is the least detrimental to our dark adapted eyes. You can buy red light torches and head lamps, but red cellophane costs bugger all and works just as well.
I wouldn't want to suggest other things as eyepieces, barlows and the such as you would be best served by first learning to use the gear that comes with your 'new' scope. There is always time for 'upgrades'.
Now, probably the best retro fit Go-To system is the Argo-Navis/Servo-Cat duo.
Argo-Navis is a digital setting circle system that guides you to thousands of DSO's once the scope is aligned. The Servo-Cat system is a drive system that when coupled to the Argo-Navis, finishes making the whole scope a true Go-To one. Servo-Cat is linked in the Argo-Navis website.
Also, look into the many other forums here on IIS. There are also visual based and photography forums, astro science, DIY, and the classifieds.
Me, I tend to lurk in the visual forum,

. That's my quirk in this hobby!
Enjoy!
Alex.