The moons are more easily visible near the limb (while still against the planet) because of the limb darkening that Jupiter shows. The limb darkening is caused by light absorption by higher levels of the Jovian atmosphere (troposphere etc). At the limb, the light reflected from Jupiter has to go through a longer distance and is therefore more highly absorbed, leading to a dark limb. Io will look brighter in the red channel since it is mostly red anyway. If you look in the blue channel, it will be much dimmer. Have I confused anyone
zac