G'Day Mark,
Nice first spectrum.
I'm a bit out of practice with my spectroscopy, so I'll stand corrected if I'm found to tell you untruths

.
It looks to me like there could be a few reasons combining to stop you from picking any features.
From your raw frame I suggest the SA is too close to the camera. The further in front of the camera you can get the SA the greater will be your dispersion. I know the Canon has a big sensor but to see -2,-1,0,1 and 2 spectra suggests its too close to see much detail.
There are a couple of lines evident in the second shot, probably Hbeta and Hgamma, but I think there are two problems with the spectrum. The first is that in the green and blue section the green and blue colours are fading towards white in the middle of the image suggesting the spectrum is overexposed. For a colour camera the brightest parts of the spectrum should be vivid colour like it is at the edges of your spectrum. The second is it looks like you have focussed on the star not the spectrum. The blue end of the spectrum is where I think the Hgamma line is visible is reasonably sharp, but less so towards the red end. Don't worry about it, we've all done it!
Looking at your spectrum I would guess the two little absorption lines on the left hand slope of the hill are Hgamma (left one -2200 on your chart) and Hbeta (right one - 2400 on your chart). Try calibrating with them and see how it goes

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The double hump at the tip of the spectrum I think might be part of the camera response between the green and blue pixels.
On the RHS of the hill, there a possible line at about 3350 on your chart... I reckon there's a slim chance its Halpha, but more likely its the telluric O2 band

(Its usually more dominant than the Ha line - but then that might be right where the spectrum dies...).
Off to a great start!
Once you get a bit more dispersion (spread the spectrum out more) I think you'll find it easier to do all the stuff you need to do. It will be harder to over expose, easier to focus on the spectrum and then the detail will come.
Al.