Hi Chris,
As Mardy suggest, there are no 'strict' rules to how to use eyepieces with what ever object, but it helps to understand what different focal lengths can do.
Mardy also hinted at the quality of the atmosphere to viewing. The greater the amount of thermal activity, the poorer the viewing quality. The thing is that the typical maximum magnification the atmosphere allows is around 120X. Double that (250X) is rare with a steady image that shimmers very, very little. Greater than that is a very rare bird. AND it doesn't matter how large your scope is or its quality - the atmosphere is a great equaliser,

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Now, focal lengths. Long focal lengths not only give the widest, steadiest views, but the background sky glow is also the brightest. This may make spotting really faint objects a challenge from the background. A trick here is to give the scope a little 'tap' to cause a vibration in the scope. This shake helps our eyes to spot the faint variations in light intensity.
Medium focal lengths, around 15mm, darken the background a little, and the faint stuff can be easier to see, but still gives a wide enough field to be able to see extended objects, such as a nebula. The slightly darkened background will also allow non-luminous components to become visible, such as the dark pillars, in bright nebulae such as in Eta Carina.
Short focal lengths, around 6mm, can be a real help with galaxies at a dark site. These EPs really darken the background an help bring out faint details. This requires a good quality EP, and a lot of patiences.
Quality EPs don't need to cost a bomb as a bit of research will show you which are the real gems at a modest price.
The above are just a description of what the various EP focal lengths can do. It is then upto you to see what various EP/scope combos best suit you and the observing site you are at, etc.
Also, have a look in the Observational and Visual forum sticky on Improving and Honing Observation Skills. There is a lot of good info there on this, and a good place to pose more questions.
Mental.