Quote:
Originally Posted by GTB_an_Owl
Steven - i have a question
why does the "heat" flow TO the "cold", and not the other way round, or an equal reaction between both ?
geoff
|
Perhaps I may try to add to answer to this question (because Steven already answered):
Quote:
Originally Posted by sjastro
The direction of time is important in thermodynamics particularly the second law which states the entropy of a system not in equilibrium must increase.
A practical demonstration of this law is that heat flows from a hot body to a cold body.
Violating the second law by reversing the direction of time leads to a major paradox:- the perpetual motion machine.
Regards
Steven
|
It is because of entropy (this is a measure of disorder of the system), something that always increases and never decreases in a closed system.
Actually, we can decrease it, but to achieve this (increase the order of the system) we have to add energy to the system.
Now, because the temperature is actually the average kinetic energy of the particles of which matter is composed, it is not hard to imagine what is happening here.
Lets say that we have a cube of something (made of atoms, of course) and lets say that the temperature of this cube is 0°K, absolute zero. That means the atoms will be perfectly still.
Lets imagine now that we have another cube, same size, of the same material, but at some temperature, lets say 100°K. And those cubes are now touching each other.
What will happen at the atomic scale?
"Hotter" atoms at the boundary will start to bump into "cold" ones of the other cube and in elastic collisions they will transfer some energy and momentum to them. They will slow down. The layer of atoms deeper in the hot cube will then start to transfer their energy to the slower ones.. etc.
After some time, all atoms of those two cubes in contact will have the same average speed and therefore kinetic energy and the temperature of both cubes will be 50°K.
The heat was transferred from hot body to cold one.
The energy was transferred from hot body to cold one.
The measure of disorder (entropy) of this system was increased - because two cubes of different temperature in contact is very organized system. Two cubes of matter in contact and at same temperature is very disorganized system.
Is it possible to "suck" heat from one cube and "store" it to another?
Yes, but we have to put energy into that system. With Peltier element for example. The energy will come from power supply current.
But for something like that to happen spontaneously, the odds are very, very, very small.
In other words, all this is because of statistical nature of behaviour of huge number or atoms.....
I hope this explanation will help you :-)