Thanks for the advice, Paul.
Yeah, I understand what you're saying. 300X would give a tight alignment, however, the star might not be very bright at all, especially through my 5" scope. Also, the higher the magnification, the faster the star 'moves' in the EP, so it kind of makes drift aligning quicker if your scope is out. I reckon my 12.5mm reticule barlowed (2X) is probably more than enough for my purposes, thought I will give a higher mag a try just for fun.
As for your comment about the planets never being in the right position....that brings me to a question.
When adjusting your altitude, you want to choose a star in the west just above the horizon. Does this star have to be dead on West? Or can it be slightly North or slightly South of West? I had nothing directly in the west except the moon yesterday, and Saturn was just North of West, so I used that.
Oh, and I saw some bright satelite or something last night, too. Well, 2 actually. One was SUPER bright...the other was tiny.
EDIT:
AAH! Whaddaya know! I just checked Heavens-above and I saw the ISS last night. Awesome! I dunno what the other one was. I can't find it...??