Philip, the luminance filter typically comes in a set with the RGB filters. You can still buy them separately though. Its important that you match what you are using for your RGB filters. I.e don't use different manufacturers as the filters will not be parfocal!
The luminance filter is usually multicoated/anti-reflective and permits the entire visual spectrum (wavelengths). They normally block IR and UV, though you can get ones that also permit these. I personally don't see much value in this, but depends on your astronomy goals. What's important is that the RGB filters are IR/UV blocked. This will ensure no colour contamination occurs and will permit the channels to be balanced.
http://www.astronomik.com/english/eng_ir.html
http://www.customscientific.com/astronomy.html
There are a few other manufactures that produce them as well. Of course, as I previously mentioned, if you don't mind refocusing you can use any filter you choose.