Heres a pic of Alpha centauri in daytime taken at 4:07 pm
Stack of 4 ISO 100 images. Pointing by Argo Navis, was bright enough to see in the camera viewfinder.
Also saw Venus, Mercury, Jupiter, Antares and Spica earlier in the day
I used Spica to do some drift alingnment to tweak the polar alingment

Scott