Thanks everyone for the critique so far, very helpful as I intend to do this over tomorrow from scratch again.
Barry- recreating the darks right now, so hopefully be able to apply them tomorrow, along with some bias frames... seriously considering buying that lightbox in the classifieds section as well.
Rowland- By clipped, do you mean that when I was playing with the histogram I may have moved the black slider too far, or when I was moving the mid tones slider?
Russell- Not too sure how photobucket works, perhaps I should move to Astrobin, but I think if you click the link then the zoom button it will give full sized image. I was a bit nervous when I was stretching as I thought I was blowing out the core of the nebule, not realising that that gets fixed up in a later step of the workflow, so will be a bit more aggressive with it tomorrow... and a bit less aggressive with the final curves adjustments

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Thanks again for your comments so far... please keep them coming. I'm very excited by my results today and I am like a sponge at the moment taking in so much information and pointers.