Alright, so making a few assumptions I think we can at least work a maximum distance out at which we'd be able to detect reflected light from the sun.
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Firstly: eye sensitivity (according to this:
http://www.lifeslittlemysteries.com/2426-human-eye.html and wikipedia). The least amount of light detectable by our eyes is at around 140 photos at a frequency of 587.8THz. From E=hf (Planck's relation) we have each photon carrying 3.9*10^-19 Joules of energy, hence a bundle of 140 of them would carry 5.46*10^-17 Joules. The "response rate" of the eye is about 1/10 seconds (
http://en.wikipedia.org/wiki/Frame_rate#Background), so we would need this bundle of photons to hit our eyes once every 0.1s for us to detect anything at all. IE we would need 5.46*10^-16 J hitting the area of our pupil per second. Now a fully dark-adapted pupil is around 9mm in diameter, which is an area of 6.36*10^-5 m^2.
Soooo to get a detectable amount of light hitting our eyes, we would need at least 8.58*10^-12 Joules per second per m^2 hitting the surface of whatever planet or spaceship we happen to be on.
Now we need to calculate the light falling on Pluto from the sun. According to Wikipedia, the average flux of light from the sun at the distance of Earth is 1360 J/s/m^2. From this, we can derive the flux from the sun at pluto (the ratio of the squares of the distances to earth/pluto times the flux at earth): 1.23 J/s/m^2!
This is way more than our supposed limiting flux of 8.58*10^-12 J/s/m^2! So at Pluto we'd almost certainly be able to see things around us.
Now for 2 light years away, the same applies. 2ly = 126 482 AU, therefore flux at 2ly from sun = (1/126482)^2 * 1360 J/s/m^2 = 8.50*10^-8 J/s/m^2. Again over our limit, but only by a factor of 4 now. It might start getting a bit tough to make out anything meaningful, but theoretically it is possible.
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So if my assumptions are correct, at both Pluto and in interstellar space 2 light years away from the sun we would still be able to detect a spaceship reflecting sunlight visually. In fact, we would need to be nearly 200 light years away from the sun for our eyes to not detect a single trace of light originating from it!
Inside the galaxy (and definitely closer to the crowded centre) it wouldn't be unlikely to have at least one bright star within 200ly of you, so perhaps while travelling within the Milky Way you'd be able to see (very vaguely) any big reflective objects around you just by starlight. But once you get out into intergalactic space ... good luck seeing anything at all.
Disclaimer: this is assuming nothing exists in the universe but you, the sun, and a spaceship that reflects 100% of the light hitting it back towards you.
In reality I'm sure we would need a lot more light than just 140 photons to meaningfully decipher anything we see, like a spaceship.
Disclaimer 2: I do not guarantee the validity of my calculations in any way. Please excuse any glaring errors.