Hi Jeremy
I've only looked through the 14mm 100 degree so cannot really comment on the 82 models. Some other people may be able to advise on these. As a starter, here are a few reviews on the ES 82s:
24mm,
6.7mm vs Meade,
Various. There are quite a few more if you have a look at Cloudynights and other sites and one here from IIS:
IIS several refs.
And for the 100s:
14mm,
another 14mm review,
and one more 14mm..,
Iceinspace review.
Hopefully, some other people may have some views on the ES 82s. My understanding from various reviews is that the 100 degree models are considered a little better, but there are trade-offs in price, performance and how wide you want to go. Can you get along to any star parties to look through any eyepieces? People in the astro community are very obliging.
Andrew