Hi David. I too am learning all the time, so much to take in. When combining darks with your light frames in DSS, the noise created from the camera is reduced. This works with images shot through lenses as well as through telescopes. And the result is, when it comes to processing, you can pull more data out of your images before the noise kicks in. Noise is the Bain of imaging, that's why people invest their hard earnt into cooled cameras.
The flats help remove the vignetting in the images. So by loading all your lights, darks and flats into DSS, it helps produce a cleaner image.
To take darks, it's simply taking a photo with the lens cap on for the same exp duration, same iso as your light frames were.
For flats, all I do is rubber band a white cotton tshirt over the end for your dew shield or lens hood, at dawn just before the sun rises so the sky is evenly illuminated, and take your pictures once again with the same exp and iso.
There a a few tutorials about using DSS and processing images on the net and YouTube is a good place for them.
I have not used a 2x on my camera lenses. When it comes to imaging through my telescope, the increase in focal length greatly increases any misalignment there is the polar alignment ( with my eq mount).
I have used two 2x barrows that gave me 4x my focal length on the moon and planets which works very well. Although with me, I realized a good quality Barlow is needed.
The idea still works on the telescope, it's just from my experience, I will need to guide with another camera and scope or use off axis guiding. Every single one of my images at present are unguided. I kind of enjoy the challenge at the moment unguiding gives. One day soon I hope to get some more equipment.
There are some absolutely magnificent images taken with just tracked camera and lens ( wide fields) out there and it can make for a refreshing change. That's how I started, buy using my camera and lens on my eq3 tracking mount, getting the basics of alignment and everything else, and seeing how long I go go before trailing started to occur. Much fun to be had.

I hope some of this helped.
Steve