Ah ok, just looked up the specs on your camera and they are impressive and full 16 bit with 80% QE coming from a OSC! maybe you'd expect that from back illuminated I would imagine.
The long focal length and narrow field should help with the LP skies that we have here in Padstow for sure but I must say that those small pixels aren't ideal for this focal length......but hey rules are made to be broken.
With your flats try about a 20,000-25,000 adu (max value not average)and make sure you didn't get a focus shift through the session or, there's no stray light getting to your sensor.
Also with a low noise OSC try just using bias frames and no darks and also a defect map.....ie, subtract a bias from your flat master, and a bias from your stacked lights instead of the dark and see how that goes.
To get a balanced background look at your histogram on the left hand side and just line up the RGB black points.
For best results work on raw files but I'm sure your aware of that anyway.....like you said....just having some fun.
Anyway all good Dave just have fun