Although I have not seen the bracket nor I have I tried to use my SkyScout in this manner here are my thoughts from my own experiences and also what I have read from other users...There has been a lot of discussion on this topic over on the Cloudy Nights forum.
My own experience is that my unit is quite sensitive to the presence of metal. So much so that I must take my watch off (metal band) or it interferes with the GPS "lock"...I've also found that the magnetic warning also comes on when I get close to my car (within a few inches). Battery shields come with the unit as well and while it seems to be a bit "hit and miss", mine does not seem to work as well without the shields in place (other users have had the opposite experience)

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Based on this experience (and without seeing the bracket) I would be careful and ask to see one demonstrated using the bracket mounted on a metal telescope. Maybe if the mout is "shielded" some way it will work...I don't know but am a skeptic.
However, the big issue with this potential use would be with respect to accuracy...again, based on my experiences I do not think that sufficient pointing/alignment accuracy would be possible for the SkyScout to be used in this manner and compare it to Digital Setting Circles (like the popular and quite wonderful Argo Navis AN).
Once properly aligned, the AN can and does deliver pinpoint accuracy of many many things in the sky...based on my experience with the SkyScout, I suspect that (assuming the mount works and the SkyScout is not distracted by the nearby metal of a telescope) I would liken it much more to a "souped up" Telrad than an Argo Navis. It would take a bit of back and forth to get accurate alignment of scope and mounted SkyScout (I think) to even be used in this manner as a few degrees of misalignment could give very big errors in pointing or finding of things.
Depending on the mount (which I have not seen in person) I'd think the viewing window of the SkyScout would also be in an akward position to use and move the scope...even then, the pointing accuracy would only put you "near" the object which is different in the AN will put you "on" the object as your "aligned view" from your eye through the SkyScout to the object might create further alignment errors.
While I do dislike discounting something that I have not seen in person (in this case the SkyScout bracket and mount), based on my experiences I find it difficult to see how a mounted SkyScout could be compared to Digital Setting Circles (DSC).
As a hand held identifier, the SkyScout is a wonderful thing...as a "poor mans" DSC...I think that they would leave a lot to be desired...
Good Luck!