Hi Carly,
Lately I've found myself pondering that same question - what would this look like/what would my experience have been had I imaged this using a CCD instead of my DSLR?
I run a stock Canon 600D. The first thing I'd probably notice if I swapped to a CCD would be greater red pickup in some of the nebula, mainly due to the replacement/removal of the UV/IR filter. This can be done on DSLR's, however it can obviously limit your ability to use the camera during the day. It's something I'm not willing to do.
The second thought that springs to mind is cooling. Many of the newer CCD's that draw my attention have a peltier device that can bring the camera ~ 25+ degrees below ambient temp. This means that thermal noise is significantly reduced, compared to say a Canon/Nikon DSLR on a warm spring/summer evening.
Sometimes dynamic range may also be better in a CCD (i.e. ability to capture both faint and bright detail in a single exposure). The oneshot color (OSC) CCD's seem reasonably popular on the forums, as the next level up from a DSLR. Your processing method would also stay fairly consistent with an OSC, which can be a big plus at times
As far as particular brands are concerned, maybe have a look at the Atik Titan Colour (circa $1000 AUD), it has cooling and says it can handle planetary & DSO, and the reviews sound pretty good. Not sure how'd you go with the camera chip size/FOV etc. with your ED80 so probably just worth checking that part.
Note - I have no affiliation with Atik or any other manufacturer/reseller. These thoughts are based only on my own research
Cheers, Evan