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What Chris said. Also, iOS devices don't sync to each other, they sync to the iTunes library on your computer (pre-iOS5) or your iTunes account in the cloud (iOS5). However, there is an option in iTunes (Preferences -> Store) that controls whether everything new you purchase on either the computer or any of your devices will also make it onto all other devices automatically. If you turn that off you are in full control of what goes onto each and every one of your devices, all of them syncing to the same iTunes lib.
Cheers
Steffen.
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