Sorry for the delay Andrew.
No, my laser cannot do angle cuts. It cuts at 90 deg only.
I have got some thin plastic from my supplier. It's about 1.5mm thick. However I haven't tried it yet and it's clear. I asked them for something suitable for picture frames and that all they sell that is thinner than 2mm. They don't have it in any other colour but may be it's possible to spray paint it in black.
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