Just to confirm Campbell's response, this is exactly what I have done with the NUC mini PC in my observatory. There is a BIOS setting that allows the computer to boot up when it sees the power switch on.
I also use an IP switch from Aviosys which allows power ports to be switched on and off via a web browser. This way you can control the power to the mini PC remotely and therefore switch on the PC as required.
CS,
Rodney
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