Not sure about the use of the USB sticks, if they contain a operating system on them or not. Within CMOS you can set the boot sequence, normally SSD/HD/USB/CD etc, that should insure that you boot from the SSD every time unless it fails to read. Then the PC will try the other bootable devices as listed.
Make a note of when you get system crashes, either after an application such as Excel has been used recently or 4k video's on YT, PC left on for days without a restart, MS updates etc.
You might see a trend forming about the crash and that might get you a solution as well.
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