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Photoshop was built for regular photography whereas Pixinsight was built for astro-photography. PS might seem more intuitive if that is what you are used to however PI has far more capability for astro-photography and it has all the parts you will ever need and more whereas the PS path will require a separate stacking solution and a bunch of add-ins.
I started with PS and purchased all the other bits along the way but have now moved to PI and that is all I use.
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