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The 64-bit edition of DSS makes a huge difference - the memory limits of 32 bit software really crippled it when it came to modern massive resolution images.
Some more RAM would be a good idea, but your system is starting to get old anyway, so I can't see much point in investing in more than an extra 8gb. Your system will use DDR3 RAM, which is now deprecated (current generation systems now use DDR4). That said, be sure to open up your case before you go shopping to make sure you actually have some empty RAM slots to put it in - your board may support up to 32gb, but that doesn't help you if all the slots are already in use!
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