Yes but...
As you say this is not possible with the CP app if you are a member of a domain and a personal or network firewall may prevent clock synchronization.
in fact most corporate and organizational firewalls will block time synchronization (ours sure does), as do some personal firewalls.
Home users should read the firewall documentation for information about unblocking network time protocol (NTP). You should be able to synchronize your clock if you switch to Windows Firewall.
OR you can use an alternate....
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