I have dabbled in Matlab but find I don't have the patience to go very far with it these days. You would certainly have much greater control over exactly what you were doing to your image but you would need to have an understanding of the functions. If you really grasp what functions like the fourier transforms and convolution do then it would be a great image manipulation tool. Linked to that would be a need to write code to step from one function to the next.
Pixinsight has all of that clad in a more user friendly shell.
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