Eyepieces with barrels larger than 2" are certainly available, but there are only a couple of manufacturers. Ziess makes some, but finding info is like pulling hen's teeth.
Siebert Optics is better known for large barrel eyepieces, all the way to 4.3" suckers. Explore Scientific makes one 3" eyepiece, but this is really just a one-of curio, and can't really say they are a dedicated large barrel EP maker.
As mentioned earlier, there are a few factors that affect the barrel size for scopes. The first one is cost. You won't see a 2" focuser in a department store cheapie. And then there is a difference in the quality of 2" focusers too. Then there is physical property of the cone of light that is typically produced is sufficient for 2" eyepieces, and to make longer focal length eyepieces with a larger barrel usually means an excessively large exit pupil with fast scopes, or introduces vignetting in most SCT's, Maks. With larger scopes (anything over 10"), it's a waste of time as these are not intended to be "sky scanners" as Joe mentioned. An 8" f/4 scope can give upto a 3° TFOV (I love mine!
), which is as large an aperture RFT sky scanner as practical, maybe include a 10" f/4 too. I certainly don't use my 17.5" for the same sky-scanner experience. There really is nothing significant to gain from a 4" 30mm eyepiece for a big dob.
But why not more larger barrel EPs, like 3", as there are now scopes being offered with 3" focusers? Mainly because there is not enough of an economic or visual gain to make 3" eyepieces for scopes that are primarily photographic instruments.
Large barrel eyepieces are intended for more specialised observatory instruments. Here again you are getting into the realm of primarily photographic instruments with a casual visual spin-off. You'll notice that all the instruments in the Siebert site that use their large eyepieces are firstly photographic instruments. And even with the longest fl EPs, the native fl of these scopes is several meters, so the TFOV will be very small.
The Mt Wilson telescopes have recently been decommissioned from professional work, and have been converted to dedicated visual instruments for the general public. You can hire the 60" and 100" instruments for your own exclusive use for a whole night!!! In the following link you'll find the tech specs of the 60" scope, f/ratio, focal length, eyepiece fl, and TFOV factors. You'll notice that the TFOV is tiny, 11 arc-minutes, despite the 100mm 4" eyepiece barrel. The blurb also says that these instruments are not good for very extended objects as these scopes' TFOV is too small for them!
As visual instruments these are very specialised instruments.
* Visual tech specs of the 60" Mt Wilson scope
* Hiring the 60" Mt Wilson scope for 1/2night or full night
* Hiring the 100" Mt Wilson scope for 1/2 night or full night