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Well, in Photoshop you can through the Curves function apply a linear profile which will usually darken a light ( or over stretched sky). There is also a Darken profile which will make the entire image uniformly darker. You can move the curve graph to tailor what your trying to darken. There is also exposure control, but without seeing an example its hard to advise. It would help to know what you are using now to process your images, and to see a sample. You might have a gradient, or have pushed the sub to far for your sky conditions.
Really rather than trying to repair it might be better to reshoot.
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