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I use one of my flats as a custom white balance for my 1000d. I use a CLS light polution filter and it certainly helps to use a custom wb.
I'm not so sure about taking a Wb shot in the day time, a white balance shot is supposed to correct for the conditions you are shooting under at the time not 5 hours earlier. But hey, I'm no expert on the subject, and thats a fact.
Sandy
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