Plausible? I think it would be. I guess it would be a slight variation on drift aligning.
My only worry is that the accuracy of the phone might not be enough to get a tight alignment.
You could however use the phone to get you within the right area, if you are close enough then you should get a minute or more with short focal length lenses, you would also have a good foundation to start a more accurate alignment routine using something like Sharpcap and a guide camera.
I think the best answer to the question will be testing it out.
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